Catalysis; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; Metals and Alloys; Materials Chemistry; General Chemistry
Abstract :
[en] Waste PLA can be upcycled to metal organic frameworks of potential high value in a one-pot synthesis scheme, where PLA depolymerisation occurs in situ. Three homochiral lactate based frameworks were successfully synthesised and characterised from PLA as a feed source, including ZnBLD. The chiral separation ability of ZnBLD was maintained.
Disciplines :
Engineering, computing & technology: Multidisciplinary, general & others
Author, co-author :
Slater, Benjamin ; Barrer Centre, Department of Chemical Engineering, Imperial College London, London SW7 2AZ, UK. Bradley.ladewig@imperial.ac.uk
Wong, So-On; Barrer Centre, Department of Chemical Engineering, Imperial College London, London, United Kingdom
Duckworth, Andrew; Barrer Centre, Department of Chemical Engineering, Imperial College London, London, United Kingdom
White, Andrew J P ; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London, United Kingdom
Hill, Matthew R ; CSIRO Private Bag, Australia
LADEWIG, Bradley Paul ; University of Luxembourg > Faculty of Science, Technology and Medicine (FSTM) > Department of Engineering (DoE) ; Barrer Centre, Department of Chemical Engineering, Imperial College London, London, United Kingdom ; Institute for Micro Process Engineering, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany
External co-authors :
yes
Language :
English
Title :
Upcycling a plastic cup: one-pot synthesis of lactate containing metal organic frameworks from polylactic acid.
Commonwealth Scientific and Industrial Research Organisation Imperial College London
Funding text :
BDS acknowledges CSIRO and Imperial College London for financial support, and thanks Dr Jason Hallett for discussions on PLA waste. The authors acknowledge Dr Charles Romain for providing PLA cups.
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