PFAS; aqueous two‐phase systems; electrospray; fluorophilic aggregation; microfluidics; pillar‐[5]‐arenes; supramolecular assembly; 3D self-assembly; Aqueous interfaces; Aqueous-two phase systems; Electrosprays; Fluorine-free; Supramolecular assemblies; Medicine (miscellaneous); Chemical Engineering (all); Materials Science (all); Biochemistry, Genetics and Molecular Biology (miscellaneous); Engineering (all); Physics and Astronomy (all)
Résumé :
[en] The interaction of perfluorinated molecules, also known as "forever chemicals" due to their pervasiveness, with their environment remains an important yet poorly understood topic. In this work, the self-assembly of perfluorinated molecules with multivalent hosts, pillar-[5]-arenes, is investigated. It is found that perfluoroalkyl diacids and pillar-[5]-arenes rapidly and strongly complex with each other at aqueous interfaces, forming solid interfacially templated films. Their complexation is shown to be driven primarily by fluorophilic aggregation and assisted by electrostatic interactions, as supported by the crystal structure of the complexes, and leads to the formation of quasi-2D phase-separated films. This self-assembly process can be further manipulated using aqueous two-phase system microdroplets, enabling the controlled formation of 3D micro-scaffolds.
Disciplines :
Physique, chimie, mathématiques & sciences de la terre: Multidisciplinaire, généralités & autres
Auteur, co-auteur :
HONAKER, Lawrence William ; Laboratory of Physical Chemistry and Soft Matter, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Gao, Tu-Nan ; Laboratory of Organic Chemistry, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands ; Biobased Chemistry and Technology, Wageningen University & Research, Wageningen, 6708 WG, The Netherlands
de Graaf, Kelsey R ; Laboratory of Physical Chemistry and Soft Matter, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands ; Laboratory of Organic Chemistry, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Bogaardt, Tessa V M ; Laboratory of Physical Chemistry and Soft Matter, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Vink, Pim ; Laboratory of Physical Chemistry and Soft Matter, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Stürzer, Tobias ; Bruker AXS GmbH, 76187, Karlsruhe, Germany
Kociok-Köhn, Gabriele ; Core Research Facility, University of Bath, Bath, BA2 7AY, UK
Zuilhof, Han ; Laboratory of Organic Chemistry, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands ; School of Pharmaceutical Science and Technology, Tianjin University, Tianjin, 300072, P. R. China ; China-Australia Institute for Advanced Materials and Manufacturing, Jiaxing University, Jiaxing, 314001, P. R. China
Miloserdov, Fedor M ; Laboratory of Organic Chemistry, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Deshpande, Siddharth ; Laboratory of Physical Chemistry and Soft Matter, Wageningen University & Research, Wageningen, 6708 WE, The Netherlands
Co-auteurs externes :
yes
Langue du document :
Anglais
Titre :
2D and 3D Self-Assembly of Fluorine-Free Pillar-[5]-Arenes and Perfluorinated Diacids at All-Aqueous Interfaces.
NWO - Nederlandse Organisatie voor Wetenschappelijk Onderzoek WUR - Wageningen University & Research
N° du Fonds :
OCENW.XS21.4.116; OCENW.XS.22.3.069
Subventionnement (détails) :
L.W.H. and S.D. acknowledge funding from the Nederlandse Organisatie voor Wetenschappelijk Onderzoek (OCENW.XS21.4.116 and OCENW.XS22.3.069). T.N.G. acknowledges funding from the VLAG graduate school of Wageningen University.
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