Article (Scientific journals)
Chiral smectic C subphases induced by mixing a bistereogenic antiferroelectric liquid crystal with a non-chiral liquid crystal
Lagerwall, Jan; Giesselmann, Frank; Rauch, Sebastian et al.
2005In Ferroelectrics, 315, p. 221-230
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Abstract :
[en] By mixing a bistereogenic antiferroelectric liquid crystal (AFLC) compound, exhibiting only the SmQ and SmCa mesophases, with the achiral N-SmC liquid crystal HOAB we could induce all three AFLC SmC-type subphases, SmCalpha, SmCbeta and SmCgamma. This seems to be in contradiction with two recent postulations regarding the subphase stability, one of which suggests that the subphases appear as a result of strong chiral interactions, the other that these phases require high smectic order something one would generally not expect in mixtures. We have studied the helical pitch, optical tilt angle, spontaneous polarization and the x-ray diffraction due to the smectic layering, as a function of mixing ratio in order to better understand the relation between phase sequence and mixture composition. The smectic layer spacing shows a strongly non-linear behavior suggesting that the basic structure of the pure AFLC substance is retained up to a HOAB content of about 75\%.
Disciplines :
Physics
Author, co-author :
Lagerwall, Jan  ;  Universität Stuttgart
Giesselmann, Frank
Rauch, Sebastian
Heppke, Gerd
Rudquist, Per
Lagerwall, S. T
Language :
English
Title :
Chiral smectic C subphases induced by mixing a bistereogenic antiferroelectric liquid crystal with a non-chiral liquid crystal
Publication date :
2005
Journal title :
Ferroelectrics
ISSN :
0015-0193
Publisher :
Taylor & Francis Ltd
Volume :
315
Pages :
221-230
Peer reviewed :
Peer Reviewed verified by ORBi
Commentary :
Dublin, Ireland
Available on ORBilu :
since 22 March 2015

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