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See detailTowards a Unified and Robust Data-Driven Approach. A Digital Transformation of Production Plants in the Age of Industry 4.0
Benedick, Paul-Lou UL

Doctoral thesis (2022)

Nowadays, industrial companies are engaging their global transition toward the fourth industrial revolution (the so-called Industry 4.0). The main objective is to increase the Overall Equipment ... [more ▼]

Nowadays, industrial companies are engaging their global transition toward the fourth industrial revolution (the so-called Industry 4.0). The main objective is to increase the Overall Equipment Effectiveness (OEE), by collecting, storing and analyzing production data. Several challenges have to be tackled to propose a unified data-driven approach to rely on, from the low-layers data collection on the machine production lines using Operational Technologies (OT), to the monitoring and more importantly the analysis of the data using Information Technologies (IT). This is all the more important for companies having decades of existence – as Cebi Luxembourg S.A., our partner in a Research, Development and Innovation project subsidised by the ministry of the Economy in Luxembourg – to upgrade their on-site technologies and move towards new business models. Artificial Intelligence (AI) now knows a real interest from industrial actors and becomes a cornerstone technology for helping humans in decision-making and data-analysis tasks, thanks to the huge amount of (sensors-based) univariate time-series available in the production floor. However, such amount of data is not sufficient for AI to work properly and to make right decisions. This also requires a good data quality. Indeed, good theoretical performance and high accuracy can be obtained when trained and tested in isolation, but AI models may still provide degraded performance in real/industrial conditions. In that context, the problem is twofold: • Industrial production systems are vertically-oriented closed systems that make difficult their communication and their cooperation with each other, and intrinsically the data collection. • Industrial companies used to implement deterministic processes. Introducing AI - that can be classified as stochastic - in the industry requires a full understanding of the potential deviation of the models in order to be aware of their domain of validity. This dissertation proposes a unified strategy for digitizing an industrial system and methods for evaluating the performance and the robustness of AI models that can be used in such data-driven production plants. In the first part of the dissertation, we propose a three-steps strategy to digitize an industrial system, called TRIDENT, that enables industrial actors to implement data collection on production lines, and in fine to monitor in real-time the production plant. Such strategy has been implemented and evaluated on a pilot case-study at Cebi Luxembourg S.A. Three protocols (OPC-UA, MQTT and O-MI/O-DF) are used for investigating their impact on the real-time performance. The results show that, even if these protocols have some disparity in terms of performance, they are suitable for an industrial deployment. This strategy has now been extended and implemented by our partner - Cebi Luxembourg S.A - in its production environment. In the second part of the thesis dissertation, we aim at investigating the robustness of AI models in industrial settings. We then propose a systematic approach to evaluate the robustness under perturbations. Assuming that i) real perturbations - in particular on the data collection - cannot be recorded or generated in real industrial environment (that could lead to production stops) and ii) a model would not be implemented before evaluating its potential deviations, limits or weaknesses, our approach is based on artificial injections of perturbations into the data sets, and is evaluated on state-of-the-art classifiers (both Machine-Learning and Deep-Learning) and data sets (in particular, public sensors-based univariate time series). First, we propose a coarse-grained study, with two artificial perturbations - called swapping effect and dropping effect - in which simple random algorithms are used. This already highlights a great disparity of the models’ robustness under such perturbations that industrial actors need to be aware of. Second, we propose a fine-grained study where instead of testing randomly some parameters' values, we used Genetic Algorithms to look for the models' limits. To do so, we define our multi-objectives optimisation problem with a fitness function as: maximising the impact of the perturbations (i.e. decreasing the most the model's accuracy), while minimising the changes in the time-series (with regards to our two parameters). This can be seen as an adversarial case, where the goal is not to exploit these weaknesses in a malicious way but to be aware of. Based on such a study, methods for making more robust the model and/or for observing such behaviour on the infrastructure could be investigated and implemented if needed. The tool developed in this latter study is therefore ready for being used in a real industrial case, where data sets and perturbations can now be fitted to the scenario. [less ▲]

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See detailDie Förderung von Wohlbefinden und Gesundheit als Aufgabe der Jugendarbeit
Meyers, Christiane UL; Biewers, Sandra UL; Heinen, Andreas UL et al

Conference given outside the academic context (2022)

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See detailThe foreign soldier’s transnational experience in the Nazi military. A biographical study of conscripts and volunteers from Luxembourg in the Wehrmacht and Waffen-SS and their military and individual experiences in WWII
Janz, Nina UL

Speeches/Talks (2022)

Coming from various occupied territories and uninvolved or neutral countries, such as Spain and Switzerland, over two million foreigners served in the ranks of the Wehrmacht and the Waffen-SS. These men ... [more ▼]

Coming from various occupied territories and uninvolved or neutral countries, such as Spain and Switzerland, over two million foreigners served in the ranks of the Wehrmacht and the Waffen-SS. These men had a significant impact on the war and on how it was experienced and conducted. How these men from more than 40 countries experienced the war in German uniform as transnational soldiers remains essentially unexamined. Focusing on those who came from Luxembourg, this paper traces the experiences of these soldiers, in order to provide a new perspective on the European experience of war. [less ▲]

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See detailContext, Prioritization, and Unexpectedness: Factors Influencing User Attitudes About Infographic and Comic Consent
Doan, Xengie Cheng UL; Selzer, Annika; Rossi, Arianna UL et al

in Web Conference Companion Volume (ACM) (2022, April 26)

Being asked to consent to data sharing is a ubiquitous experience in digital services - yet it is very rare to encounter a well designed consent experience. Considering the momentum and importance of a ... [more ▼]

Being asked to consent to data sharing is a ubiquitous experience in digital services - yet it is very rare to encounter a well designed consent experience. Considering the momentum and importance of a European data space where personal information freely and easily flows across organizations, sectors and Member States, solving the long-discussed thorny issue of "how to get consent right" cannot be postponed any further. In this paper, we describe the first findings from a study based on 24 semi-structured interviews investigating participants’ expectations and opinions toward consent in a data sharing scenario with a data trustee. We analyzed various dimensions of a consent form redesigned as a comic and an infographic, including language, information design, content and the writer-reader relationship. The results provide insights into the complexity of elements that should be considered when asking individuals to freely and mindfully disclose their data, especially sensitive information. [less ▲]

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See detailImpressions that last: representing the meaningful museum experience
Morse, Christopher UL; Niess, Jasmin UL; Bongard, Kerstin UL et al

in Behaviour and Information Technology (2022)

Research in human–computer interaction (HCI) has identified meaning as an important, yet poorly understood concept in interaction design contexts. Central to this development is the increasing emphasis on ... [more ▼]

Research in human–computer interaction (HCI) has identified meaning as an important, yet poorly understood concept in interaction design contexts. Central to this development is the increasing emphasis on designing products and technologies that promote leisure, personal fulfillment, and well-being. As spaces of profound historical significance and societal value, museums offer a unique perspective on how people construct meaning during their interactions in museum spaces and with collections, which may help to deepen notions of the content of meaningful interaction and support innovative design for cultural heritage contexts. The present work reports on the results of two studies that investigate meaning-making in museums. The first is an experience narrative study (N = 32) that analyzed 175 memorable museum visits, resulting in the establishment of 23 triggers that inform meaningful interaction in museums. A second study (N = 354) validated the comprehensiveness and generalisability of the triggers by asking participants to apply them to their own memorable museum experiences. We conclude with a framework of meaning in museums featuring the 23 triggers and two descriptive categories of temporality and scope. Our findings contribute to meaning research in HCI for museums through an articulation of the content of meaning-making in the cultural sector. [less ▲]

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See detailUser Experience Design for Cybersecurity & Privacy: addressing user misperceptions of system security and privacy
Stojkovski, Borce UL

Doctoral thesis (2022)

The increasing magnitude and sophistication of malicious cyber activities by various threat actors poses major risks to our increasingly digitized and inter-connected societies. However, threats can also ... [more ▼]

The increasing magnitude and sophistication of malicious cyber activities by various threat actors poses major risks to our increasingly digitized and inter-connected societies. However, threats can also come from non-malicious users who are being assigned too complex security or privacy-related tasks, who are not motivated to comply with security policies, or who lack the capability to make good security decisions. This thesis posits that UX design methods and practices are necessary to complement security and privacy engineering practices in order to (1) identify and address user misperceptions of system security and privacy; and (2) inform the design of secure systems that are useful and appealing from end-users’ perspective. The first research objective in this thesis is to provide new empirical accounts of UX aspects in three distinct contexts that encompass security and privacy considerations, namely: cyber threat intelligence, secure and private communication, and digital health technology. The second objective is to empirically contribute to the growing research domain of mental models in security and privacy by investigating user perceptions and misperceptions in the afore-mentioned contexts. Our third objective is to explore and propose methodological approaches to incorporating users’ perceptions and misperceptions in the socio-technical security analyses of systems. Qualitative and quantitative user research methods with experts as well as end users of the applications and systems under investigation were used to achieve the first two objectives. To achieve the third objective, we also employed simulation and computational methods. Cyber Threat Intelligence: CTI sharing platforms Reporting on a number of user studies conducted over a period of two years, this thesis offers a unique contribution towards understanding the constraining and enabling factors of security information sharing within one of the leading CTI sharing platforms, called MISP. Further, we propose a conceptual workflow and toolchain that would seek to detect user (mis)perceptions of key tasks in the context of CTI sharing, such as verifying whether users have an accurate comprehension of how far information travels when shared in a CTI sharing platform, and discuss the benefits of our socio-technical approach as a potential security analysis tool, simulation tool, or educational / training support tool. Secure & Private Communication: Secure Email We propose and describe multi-layered user journeys, a conceptual framework that serves to capture the interaction of a user with a system as she performs certain goals along with the associated user beliefs and perceptions about specific security or privacy-related aspects of that system. We instantiate the framework within a use case, a recently introduced secure email system called p≡p, and demonstrate how the approach can be used to detect misperceptions of security and privacy by comparing user opinions and behavior against system values and objective technical guarantees offered by the system. We further present two sets of user studies focusing on the usability and effectiveness of p≡p’s security and privacy indicators and their traffic-light inspired metaphor to represent different privacy states and guarantees. Digital Health Technology: Contact Tracing Apps Considering human factors when exploring the adoption as well as the security and privacy aspects of COVID-19 contact tracing apps is a timely societal challenge as the effectiveness and utility of these apps highly depend on their widespread adoption by the general population. We present the findings of eight focus groups on the factors that impact people’s decisions to adopt, or not to adopt, a contact tracing app, conducted with participants living in France and Germany. We report how our participants perceived the benefits, drawbacks, and threat model of the contact tracing apps in their respective countries, and discuss the similarities and differences between and within the study groups. Finally, we consolidate the findings from these studies and discuss future challenges and directions for UX design methods and practices in cybersecurity and digital privacy. [less ▲]

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See detailThe Luxembourg Financial Ecosystem and the European Monetary Innovation. Cas Study on KBL, LuxSE and EIB (1957-1990)
Danescu, Elena UL; Cheng, Anqi

Scientific Conference (2022, April 26)

The Luxembourg international financial centre developed considerably during the 1960s, propelled by several factors including concerted government policy, flexible regulation and a willingness to harness ... [more ▼]

The Luxembourg international financial centre developed considerably during the 1960s, propelled by several factors including concerted government policy, flexible regulation and a willingness to harness opportunities at international level (such as the 1963 US interest equalisation tax and the Bundesbank provisions introduced in 1968 and 1974). The decision to establish various Community institutions (the ECSC High Authority in 1952) and European funding institutions (the European Investment Bank in 1968) in the country also had a decisive impact. The currency union with Belgium (BLEU, 1921) and the absence of a Luxembourg Central Bank made these developments all the more significant. Drawing on archives and oral history sources, this paper aims to illustrate the complexity and originality that characterised the development of the conceptual, political and regulatory context in Luxembourg in the 1960s-1990s, in what can be seen as a sui generis experiment and preparation for EMU. It will explore the changing financial ecosystem in Luxembourg and the collaborative efforts by its main stakeholders (banks, regulatory authorities, individuals, networks) - with a focus on KBL, LuxSE and EIB - to encourage financial and monetary innovation (via the EUA, ECU, and Eurco) before the introduction of the European single currency and to pave the way for the establishment and consolidation of the euro [less ▲]

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See detailData Analysis for Insurance: Recommendation System Based on a Multivariate Hawkes Process
Lesage, Laurent UL

Doctoral thesis (2022)

The objective of the thesis is to build a recommendation system for insurance. By observing the behaviour and the evolution of a customer in the insurance context, customers seem to modify their insurance ... [more ▼]

The objective of the thesis is to build a recommendation system for insurance. By observing the behaviour and the evolution of a customer in the insurance context, customers seem to modify their insurance cover when a significant event happens in their life. In order to take into account the influence of life events (e.g. marriage, birth, change of job) on the insurance covering selection from customers, we model the recommendation system with a Multivariate Hawkes Process (MHP), which includes several specific features aiming to compute relevant recommendations to customers from a Luxembourgish insurance company. Several of these features are intent to propose a personalized background intensity for each customer thanks to a Machine Learning model, to use triggering functions suited for insurance data or to overcome flaws in real-world data by adding a specific penalization term in the objective function. We define a complete framework of Multivariate Hawkes Processes with a Gamma density excitation function (i.e. estimation, simulation, goodness-of-fit) and we demonstrate some mathematical properties (i.e. expectation, variance) about the transient regime of the process. Our recommendation system has been back-tested over a full year. Observations from model parameters and results from this back-test show that taking into account life events by a Multivariate Hawkes Process allows us to improve significantly the accuracy of recommendations. The thesis is presented in five chapters. Chapter 1 explains how the background intensity of the Multivariate Hawkes Process is computed thanks to a Machine Learning algorithm, so that each customer has a personalized recommendation. Chapter 1 is shown an extended version of the method presented in [1], in which the method is used to make the algorithm explainable. Chapter 2 presents a Multivariate Hawkes Processes framework in order to compute the dependency between the propensity to accept a recommendation and the occurrence of life events: definitions, notations, simulation, estimation, properties, etc. Chapter 3 presents several results of the recommendation system: estimated parameters of the model, effects of contributions, backtesting of the model’s accuracy, etc. Chapter 4 presents the implementation of our work into a R package. Chapter 5 concludes on the contributions and perspectives opened by the thesis. [less ▲]

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See detailMachine learning in Public Health: Relevant applications in ageing populations
Leist, Anja UL

Presentation (2022, April 25)

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See detailFederated Geometric Monte Carlo Clustering to Counter Non-IID Datasets
Lucchetti, Federico UL; Maria, Fernandes; Lydia, Chen et al

E-print/Working paper (2022)

Federated learning allows clients to collaboratively train models on datasets that are acquired in different locations and that cannot be exchanged because of their size or regulations. Such collected ... [more ▼]

Federated learning allows clients to collaboratively train models on datasets that are acquired in different locations and that cannot be exchanged because of their size or regulations. Such collected data is increasingly non-independent and non- identically distributed (non-IID), negatively affecting training accuracy. Previous works tried to mitigate the effects of non- IID datasets on training accuracy, focusing mainly on non-IID labels, however practical datasets often also contain non-IID features. To address both non-IID labels and features, we propose FedGMCC1, a novel framework where a central server aggregates client models that it can cluster together. FedGMCC clustering relies on a Monte Carlo procedure that samples the output space of client models, infers their position in the weight space on a loss manifold and computes their geometric connection via an affine curve parametrization. FedGMCC aggregates connected models along their path connectivity to produce a richer global model, incorporating knowledge of all connected client models. FedGMCC outperforms FedAvg and FedProx in terms of convergence rates on the EMNIST62 and a genomic sequence classification datasets (by up to +63%). FedGMCC yields an improved accuracy (+4%) on the genomic dataset with respect to CFL, in high non-IID feature space settings and label incongruency. [less ▲]

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See detailRKHS Based State Estimator for Radar Sensor in Indoor Application
Kumar Singh, Uday UL; Shankar, Bhavani; Alaee, Mohammad

Scientific Conference (2022, April 23)

For the estimation of targets’ states (location, velocity, and acceleration) from nonlinear radar measurements, usually, the improved version of well known Kalman filter: extended Kalman filter (EKF) and ... [more ▼]

For the estimation of targets’ states (location, velocity, and acceleration) from nonlinear radar measurements, usually, the improved version of well known Kalman filter: extended Kalman filter (EKF) and unscented Kalman filter (UKF) are used. However, EKF and UKF approximates the nonlinear measurement function either by Jacobian or using sigma points. Consequently, because of the approximation of the measurement function, the EKF and UKF cannot achieve high estimation accuracy. The potential solution is to replace the approximation of nonlinear measurement function with its estimate, obtained in high dimensional reproducing kernel Hilbert space (RKHS). An ample amount of research has been done in this direction, and the combined filter is termed RKHS based Kalman filter. However, there is a shortage of literature dealing with estimating the dynamic state of the target in an indoor environment using RKHS based Kalman filter. Therefore, in this paper, we propose the use of RKHS based Kalman filter for indoor application. Specifically, we validate the suitability of the RKHS based Kalman filtering approach using simulations performed over three different target motion models. [less ▲]

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See detailThe Role of Country-Level Availability and Generosity of Healthcare Services, and Old-Age Ageism for Missed Healthcare during the COVID-19 Pandemic Control Measures in Europe
Settels, Jason UL; Leist, Anja UL

in Journal of Aging and Health (2022)

Objectives: The effects of the COVID-19 outbreak on non-COVID-19-related healthcare need further investigation. Methods: Using the Survey of Health, Ageing and Retirement in Europe’s COVID-19 module (2020 ... [more ▼]

Objectives: The effects of the COVID-19 outbreak on non-COVID-19-related healthcare need further investigation. Methods: Using the Survey of Health, Ageing and Retirement in Europe’s COVID-19 module (2020) (N = 57,025), country-level data from the European Social Survey (2008) and OECD (2020), and logistic regressions, this study examines predictors of older Europeans’ forgone, postponed, and denied healthcare during the pandemic. Results: Country-level availability of physicians, healthcare systems’ generosity, and beliefs that older persons burden healthcare systems all increased forgone healthcare. Healthcare system generosity increased postponed and denied healthcare. Greater medical resources decreased denied healthcare. Furthermore, missed healthcare varied by individual-level gender (higher rates among women), age, education, and health. Discussion: This study reveals predictors of missed healthcare during the pandemic. To decrease unintended health consequences of a pandemic, both individual-level determinants, such as gender and health, and contextual-level determinants, such as healthcare systems’ characteristics, should be considered in research and practice. [less ▲]

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See detailSecuring Industrial Internet of Things Against Botnet Attacks Using Hybrid Deep Learning Approach
Hasan, Tooba; Malik, Jahanzaib; Bibi, Iram et al

in IEEE Transactions on Network Science and Engineering (2022)

Industrial Internet of Things (IIoT) formation of richer ecosystem of intelligent interconnected devices while enabling new levels of digital innovation has essentially transformed and revolutionized ... [more ▼]

Industrial Internet of Things (IIoT) formation of richer ecosystem of intelligent interconnected devices while enabling new levels of digital innovation has essentially transformed and revolutionized global manufacturing and industry 4.0. Conversely, the prevalent distributed nature of IIoT, Industrial 5G, underlying IoT sensing devices, IT/OT convergence, Edge Computing, and Time Sensitive Networking makes it an impressive and potential target for cyber-attackers. Multi-variant persistent and sophisticated bot attacks are considered catastrophic for connects IIoTs. Besides, botnet attack detection is extremely complex and decisive. Thus, efficient and timely detection of IIoT botnets is a dire need of the day. We propose a hybrid intelligent Deep Learning (DL)-enabled mechanism to secure IIoT infrastructure from lethal and sophisticated multi-variant botnet attacks. The proposed mechanism has been rigorously evaluated with latest available dataset, standard and extended performance evaluation metrics, and current DL benchmark algorithms. Besides,cross validation of our results are also performed to clearly show overall performance. The proposed mechanisms outperforms in identifying accurately multi-variant sophisticated bot attacks. Besides, our proposed technique also show promising results in terms of speed efficiency. [less ▲]

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See detailThe positional value of education in the Americas: dynamics of inequality in labour market returns for highly unequal countries, 2000-2019
Ceron, Francisco UL; Chauvel, Louis UL

Scientific Conference (2022, April 22)

The article examines how the labour market value of education has changed in the context of the expansion of higher education. However, one drawback is understanding how it generates differences between ... [more ▼]

The article examines how the labour market value of education has changed in the context of the expansion of higher education. However, one drawback is understanding how it generates differences between high and low-skilled labour markets, particularly in contexts of high inequality and informality. This could be linked to specific mechanisms by which employers value educational credentials as signalled skills. Using the Luxembourg Income Study (LIS), we analyse trends over two decades in 11 American countries. Our results confirm the previous results for the claim that education has become increasingly positional, compared with the absolute model of education. However, we find that the relative gains in wages for workers with higher levels of education, as the pool of higher education graduates expand over time, increased only slightly in high-skilled occupations, while their relative gains decreased for lower-skilled occupations. This trend is present in both absolute and positional models of education. Moreover, when looking at the structure of labour markets in terms of the linkage between educational credentials and occupational groups, we higher the tertiary education specificity of occupations, the higher the earnings for workers with advantaged positions. These findings are consistent with processes of displacement of low-skilled workers due to increasing competition among highly educated workers, from the positional model of education. [less ▲]

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See detailMarina Hands sur la scène théâtrale française : la légitimité d'une « parole autorisée »
Deregnoncourt, Marine UL

in Théâtres du Monde (2022)

Fille de Ludmila Mikaël et de Terry Hands, Marina Hands se voit décerner, en 2019, le « prix du Brigadier » pour le rôle de Marina dans Sœurs (Marina & Audrey) de Pascal Rambert. Comment Marina Hands ... [more ▼]

Fille de Ludmila Mikaël et de Terry Hands, Marina Hands se voit décerner, en 2019, le « prix du Brigadier » pour le rôle de Marina dans Sœurs (Marina & Audrey) de Pascal Rambert. Comment Marina Hands parvient-elle à s’imposer en tant que femme et artiste, étant elle-même fille d’artistes ? En d’autres termes, que se passe-t-il pour elle en coulisses et derrière la scène ? L’article, divisé en trois parties, que l’on souhaite vous proposer, en vue d’apporter humblement et modestement notre pierre à l’édifice du numéro 32 de Théâtres du Monde, entend répondre à ces deux questions centrales. Pour ce faire, nous envisagerons, tout d’abord, Marina Hands, l’artiste, et sa réaction face à ce prix. Ensuite, nous aborderons Marina Hands, la femme, en tant que fille d’artistes. Nous nous focaliserons ainsi sur le lien sororal qui l’unit à sa mère, Ludmila Mikaël. Nous en viendrons, in fine, à la sororité existant entre elle et Audrey Bonnet, interprète d’Audrey dans le spectacle rambertien précité. [less ▲]

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See detailArchitectures and Synchronization Techniques for Distributed Satellite Systems: A Survey
Martinez Marrero, Liz UL; Merlano Duncan, Juan Carlos UL; Querol, Jorge UL et al

in IEEE Access (2022), 10

Cohesive Distributed Satellite Systems (CDSSs) is a key enabling technology for the future of remote sensing and communication missions. However, they have to meet strict synchronization requirements ... [more ▼]

Cohesive Distributed Satellite Systems (CDSSs) is a key enabling technology for the future of remote sensing and communication missions. However, they have to meet strict synchronization requirements before their use is generalized. When clock or local oscillator signals are generated locally at each of the distributed nodes, achieving exact synchronization in absolute phase, frequency, and time is a complex problem. In addition, satellite systems have significant resource constraints, especially for small satellites, which are envisioned to be part of the future CDSSs. Thus, the development of precise, robust, and resource-efficient synchronization techniques is essential for the advancement of future CDSSs. In this context, this survey aims to summarize and categorize the most relevant results on synchronization techniques for Distributed Satellite Systems (DSSs). First, some important architecture and system concepts are defined. Then, the synchronization methods reported in the literature are reviewed and categorized. This article also provides an extensive list of applications and examples of synchronization techniques for DSSs in addition to the most significant advances in other operations closely related to synchronization, such as inter-satellite ranging and relative position. The survey also provides a discussion on emerging data-driven synchronization techniques based on Machine Learning (ML). Finally, a compilation of current research activities and potential research topics is proposed, identifying problems and open challenges that can be useful for researchers in the field. [less ▲]

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See detailMetal-oxide nanostructures for low-power gas sensors
Bhusari, Rutuja Dilip UL

Doctoral thesis (2022)

For gas sensing applications, metal oxide (MOx) nanostructures have demonstrated attractive properties due their large surface-over-volume ratio, combined with the possibility to use multiple materials ... [more ▼]

For gas sensing applications, metal oxide (MOx) nanostructures have demonstrated attractive properties due their large surface-over-volume ratio, combined with the possibility to use multiple materials and multi-functional properties. For MOx chemiresistive gas sensors, the temperature activated interaction of atmospheric oxygen with MOx surface plays a major role in the sensor kinetics as it leads to oxygen adsorption-desorption reactions, that eventually affects the gas sensing performance. Thus, MOx sensors are operated at high temperatures to achieve the desired sensitivity. This high temperature operation of MOx sensors limits their application in explosive gas detection, reduces the sensor lifetime and causes power consumption. To overcome these drawbacks of MOx sensors, researchers have proposed the use of heterostructures and light activation as alternatives. In this thesis, we aim to develop low power consuming MOx sensors using these solutions. We show the template-free bottom-up synthesis and shape control of copper hydroxide-based nanostructures grown in liquid phase which act as templates for formation of CuO nanostructures. Precise control over the pH of the solution and the reaction temperature led to intended tuning of the morphology and chemical composition of the nanostructures. We contemplate upon the rationale behind this change in shape and material as CuO nanostructures are further used in a heterostructure. We discuss synthesis and characterisation of CuO bundles and Cu2O truncated cubes, former of which lead to very interesting gas sensing properties and application. Devices made from CuO bundles network are investigated for their electrical and oxygen adsorption- desorption properties as a gas sensor. It was observed that the sensor has faster response and recovery in as deposited condition in comparison to annealed sensor. A detailed inspection of response and recovery curves enabled us to derive parameters like time constants, reaction constants and diffusion coefficients for CuO bundles, an analysis that is scarcely performed on p-type materials. Investigation of the derived parameters, role of network junctions and a hydroxylated CuO surface leads us to discuss the hypotheses for the contributing processes. CuO bundles show conduction transients upon exposure to reducing gas H2 and temperature-based inversion of response upon exposure to reducing gas CO. This has not been reported in literature for CuO exposed to H2 and/or CO. Armed with this fundamental knowledge of gas sensing, we choose ZnO, n type transducer material, and CuO, p type materials with lower band gap and higher absorption in the visible range to synthesise a heterostructure. However, sol-gel synthesis of ZnO and CuO nanostructures have different reactions parameters, like temperature, pH, etc., and do not show natural affinity to grow on the other material. These challenges are overcome by implementing a stepped synthesis procedure to fabricate a heterostructure with Cu-based nanoplatelets on ZnO Nanorods, also represented as CuO@ZnO heterostructure in this thesis. We finally demonstrate electrical and functional characterisation of CuO@ZnO heterostructure. The heterostructure responds differently to tested gasses as compared to its constituent nanostructure ZnO nanorods and a reference CuO nanostructure, CuO bundles. This is an unexpected result as heterostructures usually show response type similar to their base material but with an enhanced sensor response. We present a possible application of e-nose that can differentiate qualitatively between CO, NO2 and ethanol, using the heterostructure, ZnO nanorods and CuO bundles together. [less ▲]

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See detailAcademic Profile Development: An Investigation of Differentiation Processes Based on Students' Achievement and Grade Level
Breit, Moritz; Brunner, Martin; Fischbach, Antoine UL et al

Scientific Conference (2022, April 21)

Academic achievement profiles affect students’ further development, i.e., by informing educational and professional choices. However, there is a lack of knowledge on the mechanisms behind the development ... [more ▼]

Academic achievement profiles affect students’ further development, i.e., by informing educational and professional choices. However, there is a lack of knowledge on the mechanisms behind the development of academic profiles. For research on cognitive ability profiles, specifically differentiation processes, statistical tools have been developed. In the present article, we transfer these methods for differentiation research to academic achievement data. We examine differentiation depending on students’ general level of achievement and grade level in a large Luxembourgish student sample. Students’ achievements in German, French, and Math were assessed within the Luxembourg school monitoring program. We found more balanced academic profiles with increasing achievement level. We further found more balanced profiles with increasing grade level and a positive interaction effect. [less ▲]

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