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See detailNonequilibrium thermodynamics of non-ideal chemical reaction networks
Avanzini, Francesco UL; Penocchio, Emanuele UL; Falasco, Gianmaria UL et al

in Journal of Chemical Physics (2021), 154

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory that accounts for interactions ... [more ▼]

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory that accounts for interactions between chemical species within a mean-field approach using activity coefficients. Thermodynamic consistency requires that rate equations do not obey standard mass-action kinetics but account for the interactions with concentration dependent kinetic constants. Many features of the ideal formulations are recovered. Crucially, the thermodynamic potential and the forces driving non-ideal chemical systems out of equilibrium are identified. Our theory is general and holds for any mean-field expression of the interactions leading to lower bounded free energies. [less ▲]

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See detailChemical cloaking
Avanzini, Francesco UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in Physical Review. E. (2020), 101(6), 060102

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See detailThermodynamics of non-elementary chemical reaction networks
Avanzini, Francesco UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in New Journal of Physics (2020), 22(9), 093040

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See detailThermodynamics of Chemical Waves
Avanzini, Francesco UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in Cornell University (2019)

Detailed reference viewed: 342 (4 UL)