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See detailNonequilibrium thermodynamics of light-induced reactions
Penocchio, Emanuele UL; Rao, Riccardo; Esposito, Massimiliano UL

in Journal of Chemical Physics (2021), 155

Current formulations of nonequilibrium thermodynamics of open chemical reaction networks only consider chemostats as free-energy sources sustaining nonequilibrium behaviors. Here, we extend the theory to ... [more ▼]

Current formulations of nonequilibrium thermodynamics of open chemical reaction networks only consider chemostats as free-energy sources sustaining nonequilibrium behaviors. Here, we extend the theory to include incoherent light as a source of free energy. We do so by relying on a local equilibrium assumption to derive the chemical potential of photons relative to the system they interact with. This allows us to identify the thermodynamic potential and the thermodynamic forces driving light-reacting chemical systems out-of-equilibrium. We use this framework to treat two paradigmatic photochemical mechanisms describing light-induced unimolecular reactions—namely, the adiabatic and diabatic mechanisms—and highlight the different thermodynamics they lead to. Furthermore, using a thermodynamic coarse-graining procedure, we express our findings in terms of commonly measured experimental quantities, such as quantum yields. [less ▲]

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See detailNonequilibrium thermodynamics of non-ideal chemical reaction networks
Avanzini, Francesco UL; Penocchio, Emanuele UL; Falasco, Gianmaria UL et al

in Journal of Chemical Physics (2021), 154

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory that accounts for interactions ... [more ▼]

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory that accounts for interactions between chemical species within a mean-field approach using activity coefficients. Thermodynamic consistency requires that rate equations do not obey standard mass-action kinetics but account for the interactions with concentration dependent kinetic constants. Many features of the ideal formulations are recovered. Crucially, the thermodynamic potential and the forces driving non-ideal chemical systems out of equilibrium are identified. Our theory is general and holds for any mean-field expression of the interactions leading to lower bounded free energies. [less ▲]

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See detailHeat transport in overdamped quantum systems
Salehi Kadijani, Mohammad Sadeq UL; Schmidt, Thomas UL; Esposito, Massimiliano UL et al

in Physical Review. B (2020)

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See detailDissipation-Time Uncertainty Relation
Falasco, Gianmaria UL; Esposito, Massimiliano UL

in Physical Review Letters (2020), 125(12), 120604

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See detailEffective thermodynamics of two interacting underdamped Brownian particles
Herpich, Tim UL; Shayanfard, Kamran; Esposito, Massimiliano UL

in Physical Review. E. (2020), 101

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See detailOpen questions on nonequilibrium thermodynamics of chemical reaction networks
Esposito, Massimiliano UL

in Communications Chemistry (2020), 3(107), 1--3

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See detailMeasurability of nonequilibrium thermodynamics in terms of the Hamiltonian of mean force
Strasberg, Philipp; Esposito, Massimiliano UL

in Physical Review. E. (2020), 101(5), 050101

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See detailChemical cloaking
Avanzini, Francesco UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in Physical Review. E. (2020), 101(6), 060102

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See detailThermodynamics of non-elementary chemical reaction networks
Avanzini, Francesco UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in New J. Phys. (2020), 22(9), 093040

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See detailStrong current response to slow modulation: A metabolic case-study
Forastiere, Danilo UL; Falasco, Gianmaria UL; Esposito, Massimiliano UL

in Journal of Chemical Physics (2020), 152(13), 134101

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See detailEfficiency Fluctuations of Stochastic Machines Undergoing a Phase Transition
Vroylandt, Hadrien; Esposito, Massimiliano UL; Verley, Gatien

in Physical Review Letters (2020), 124(25), 250603

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See detailUnifying thermodynamic uncertainty relations
Falasco, Gianmaria UL; Esposito, Massimiliano UL; Delvenne, Jean-Charles

in New J. Phys. (2020), 22(5), 053046

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See detailStochastic thermodynamics of all-to-all interacting many-body systems
Herpich, Tim; Cossetto, Tommaso UL; Falasco, Gianmaria UL et al

in New J. Phys. (2020), 22(6), 063005

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See detailStochastic and Quantum Thermodynamics of Driven RLC Networks
Freitas, Jose Nahuel UL; Delvenne, Jean-Charles; Esposito, Massimiliano UL

in Physical Review X (2020)

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See detailHeat transport in overdamped quantum systems
Kadijani, Sadeq S.; Schmidt, Thomas UL; Esposito, Massimiliano UL et al

in Physical Review. B (2020), 102

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See detailStochastic and Quantum Thermodynamics of Driven RLC Networks
Freitas, Nahuel; Delvenne, Jean-Charles; Esposito, Massimiliano UL

in Phys. Rev. X (2020), 10(3), 031005

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See detailWork Statistics across a Quantum Phase Transition
Fei, Zhaoyu; Freitas, Nahuel; Cavina, Vasco UL et al

in Physical Review Letters (2020), 124(17), 170603

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See detailThermodynamics of optical Bloch equations
Elouard, Cyril; Herrera-Marti, David; Esposito, Massimiliano UL et al

in New J. Phys. (2020), 22(10), 103039

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See detailMicro-reversibility and thermalization with collisional baths
Ehrich, Jannik; Esposito, Massimiliano UL; Barra, Felipe et al

in Physica A. Statistical Mechanics and its Applications (2020)

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See detailEntropy Production in Open Systems: The Predominant Role of Intraenvironment Correlations
Ptaszyński, Krzysztof; Esposito, Massimiliano UL

in PHYSICAL REVIEW LETTERS (2019)

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