References of "Solar Energy Materials and Solar Cells"
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See detailRole of cation-mediated recombination in perovskite solar cells
Singh, Ajay UL; Kaiser, Waldemar; Gagliardi, Alessio

in Solar Energy Materials and Solar Cells (2021)

The origin of the hysteresis in the current–voltage (J–V) characteristics in perovskite solar cells (PSCs) is one of the most debated topics of recent years. Hysteretic effects are connected with the slow ... [more ▼]

The origin of the hysteresis in the current–voltage (J–V) characteristics in perovskite solar cells (PSCs) is one of the most debated topics of recent years. Hysteretic effects are connected with the slow redistribution of ionic defects during the voltage sweep. Existing literature focuses on the potential screening due to accumulated ions, solely, while neglecting the possibility of charge trapping and subsequent recombination via ions. We investigate the role of cation-mediated recombination of ions using time-dependent drift–diffusion simulations in MAPbI3 PSCs. Slow-moving cations are considered as traps for the electrons. Trapped electrons can subsequently recombine non-radiatively with holes. We analyze the role of the cation-mediated trapping and its parameters (capture coefficient, cation energy, ion mobility) as well as the scan rate on the device performance. For shallow cation energies, a decrease in open-circuit voltage and slight enhancement in hysteresis is observed. Deep cation energies lead to a substantial deterioration of device performance and large hysteresis enhancement. The presented study emphasizes the importance of considering the interaction of ions with charge carriers beyond the simple electrostatic models to improve our understanding of PSCs. [less ▲]

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See detailOn the origin of band-tails in kesterite
Rey, Germain UL; Larramona, G.; Bourdais, S. et al

in Solar Energy Materials and Solar Cells (2017)

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See detailSecondary phase formation during monoclinic Cu2SnS3 growth for solar cell application
De Wild, Jessica UL; Robert, Erika UL; El Adib, Brahime et al

in Solar Energy Materials and Solar Cells (2016)

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See detailNanoscale investigations of the electronic surface properties of Cu(In,Ga)Se$_2$ thin films by scanning tunneling spectroscopy
Mönig, H.; Caballero, R.; Kaufmann, C. A. et al

in Solar Energy Materials and Solar Cells (2011), 95

In this work we investigate the electronic surface properties of polycrystalline Cu(In,Ga)Se$_2$ thin films by locally resolved scanning tunneling spectroscopy (STS). From current imaging tunneling ... [more ▼]

In this work we investigate the electronic surface properties of polycrystalline Cu(In,Ga)Se$_2$ thin films by locally resolved scanning tunneling spectroscopy (STS). From current imaging tunneling spectroscopy (CITS) maps of an area of we observe distinct granular inhomogeneities, where current-voltage ($I(U)$) spectra differ from grain to grain and vary between metallic and semiconducting characteristics. Due to the high density of defect states at the Cu(In,Ga)Se$_2$ surface, the metallic $I(U)$ characteristics is not surprising. In the case of the semiconducting $I(U)$ characteristics, we suggest a preferential oxidation of particular grains, which passivates defect levels at the surface. This is supported by the presence of gallium and indium oxides detected by global X-ray photoelectron spectroscopy. Furthermore, we recorded $I(U)$ spectra from different grains under supra band gap laser illumination, which always show semiconducting characteristics. This behavior can be explained by a saturated occupation of defect states by photoexcited charge carriers. By evaluating differential conductance $(dI/dU)$ spectra under illumination from various grains, we estimate the average surface band gap to and compare the valence band onset with results from macroscopic ultraviolet photoelectron spectroscopy. The high lateral resolution of our CITS data allows also to study electronic properties at grain boundaries, which are discussed with regard to a recent STS study on a non-oxidized sample. [less ▲]

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