Reference : Manifestation of charged and strained graphene layers in the Raman response of graphi...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Physics
http://hdl.handle.net/10993/12219
Manifestation of charged and strained graphene layers in the Raman response of graphite intercalation compounds.
English
Chacon-Torres, Julio C. [Faculty of Physics, University of Vienna , Strudlhofgasse 4, A-1090 Vienna, Austria.]
Wirtz, Ludger mailto [University of Luxembourg > Faculty of Science, Technology and Communication (FSTC) > Physics and Materials Science Research Unit >]
Pichler, Thomas [Faculty of Physics, University of Vienna , Strudlhofgasse 4, A-1090 Vienna, Austria.]
2013
ACS Nano
American Chemical Society
7
10
9249
Yes (verified by ORBilu)
International
1936-0851
1936-086X
Washington
DC
[en] We present detailed multifrequency resonant Raman measurements of potassium graphite intercalation compounds (GICs). From a well-controlled and consecutive in situ intercalation and high-temperature deintercalation approach the response of each stage up to stage VI is identified. The positions of the G and 2D lines as a function of staging depend on the charge transfer from K to the graphite layers and on the lattice expansion. Ab initio calculations of the density and the electronic band structure demonstrate that most (but not all) of the transferred charge remains on the graphene sheets adjacent to the intercalant layers. This leads to an electronic decoupling of these "outer" layers from the ones sandwiched between carbon layers and consequently to a decoupling of the corresponding Raman spectra. Thus, higher stage GICs offer the possibility to measure the vibrations of single, double, and multilayer graphene under conditions of biaxial strain. This strain can additionally be correlated to the in-plane lattice constants of GICs determined by X-ray diffraction. The outcome of this study demonstrates that Raman spectroscopy is a very powerful tool to identify local internal strain in pristine and weakly charged single and few-layer graphene and their composites, yielding even absolute lattice constants.
http://hdl.handle.net/10993/12219
10.1021/nn403885k

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