References of "Garoli, Denis"
     in
Bookmark and Share    
Full Text
Peer Reviewed
See detailElectrophoretic Deposition of WS2 Flakes on Nanoholes Arrays—Role of Used Suspension Medium
Mosconi, Dario; Giovannini, Giorgia; Maccaferri, Nicolò UL et al

in Materials (2019), 12(20), 3286

Here we optimized the electrophoretic deposition process for the fabrication of WS2 plasmonic nanohole integrated structures. We showed how the conditions used for site-selective deposition influenced the ... [more ▼]

Here we optimized the electrophoretic deposition process for the fabrication of WS2 plasmonic nanohole integrated structures. We showed how the conditions used for site-selective deposition influenced the properties of the deposited flakes. In particular, we investigated the effect of different suspension buffers used during the deposition both in the efficiency of the process and in the stability of WS2 flakes, which were deposited on an ordered arrays of plasmonic nanostructures. We observed that a proper buffer can significantly facilitate the deposition process, keeping the material stable with respect to oxidation and contamination. Moreover, the integrated plasmonic structures that can be prepared with this process can be applied to enhanced spectroscopies and for the preparation of 2D nanopores. [less ▲]

Detailed reference viewed: 27 (0 UL)
Full Text
Peer Reviewed
See detailPlasmonic nanopores for single-molecule detection and manipulation: towards sequencing applications
Garoli, Denis; Yamazaki, Hirohito; Maccaferri, Nicolò UL et al

in Nano Letters (2019)

Detailed reference viewed: 42 (3 UL)
Full Text
Peer Reviewed
See detailA hybrid metal–dielectric zero mode waveguide for enhanced single molecule detection
Zambrana-Puyalto, Xavier; Ponzellini, Paolo; Maccaferri, Nicolò UL et al

in Chemical Communications (2019)

We fabricated hybrid metal–dielectric nanoslots and measured their optical response at three different wavelengths. The nanostructure is fabricated on a bilayer film formed by the sequential deposition of ... [more ▼]

We fabricated hybrid metal–dielectric nanoslots and measured their optical response at three different wavelengths. The nanostructure is fabricated on a bilayer film formed by the sequential deposition of silicon and gold on a transparent substrate. The optical characterization is done via fluorescence spectroscopy measurements. We characterized the fluorescence enhancement, as well as the lifetime and the detection volume reduction for each wavelength. We observe that the hybrid metal–dielectric nanoslots behave as enhanced zero mode waveguides in the near-infrared spectral region. Their detection volume is such that they can perform enhanced single-molecule detection at tens of μM. We compared their behavior with that of a golden ZMW, and we demonstrated that the dielectric silicon layer improves both the optical performance and the stability of the device. [less ▲]

Detailed reference viewed: 20 (0 UL)
Full Text
Peer Reviewed
See detailSite-selective functionalization of plasmonic nanopores for enhanced fluorescence emission rate and Förster Resonance Energy Transfer
Zambrana-Puyalto, Xavier; Maccaferri, Nicolò UL; Ponzellini, Paolo et al

in Nanoscale Advances (2019), 1(6), 2454-2461

In this work, we use a site-selective functionalization strategy to decorate plasmonic nanopores with fluorescent dyes. Using an easy and robust fabrication method, we manage to build plasmonic rings on ... [more ▼]

In this work, we use a site-selective functionalization strategy to decorate plasmonic nanopores with fluorescent dyes. Using an easy and robust fabrication method, we manage to build plasmonic rings on top of dielectric nanotubes with different inner diameters. The modulation of the dimension of the nanopores allows us to tailor their field confinement and their Purcell Factor in the visible spectral range. In order to investigate how the changes in geometry influence the fluorescence emission rate efficiency, thiol-conjugated dyes are anchored on the plasmonic ring, thus forming a functional nanopore. We study the lifetime of ATTO 520 and ATTO 590 attached in two different configurations: single dye, and FRET pair. For the single dye configuration, we observe that the lifetime of both single dyes decreases as the size of the nanopore is reduced. The smallest nanopores yield an experimental Purcell Factor of 6. For the FRET pair configuration, we measure two regimes. For large nanopore sizes, the FRET efficiency remains constant. Whereas for smaller sizes, the FRET efficiency increases from 30 up to 45% with a decrease of the nanopore size. These findings, which have been supported by numerical simulations, may open new perspectives towards energy transfer engineering in plasmonic nanopores with potential applications in photonics and biosensing, in particular in single-molecule detection and sequencing.In this work, we use a site-selective functionalization strategy to decorate plasmonic nanopores with fluorescent dyes. Using an easy and robust fabrication method, we manage to build plasmonic rings on top of dielectric nanotubes with different inner diameters. The modulation of the dimension of the nanopores allows us to tailor their field confinement and their Purcell Factor in the visible spectral range. In order to investigate how the changes in geometry influence the fluorescence emission rate efficiency, thiol-conjugated dyes are anchored on the plasmonic ring, thus forming a functional nanopore. We study the lifetime of ATTO 520 and ATTO 590 attached in two different configurations: single dye, and FRET pair. For the single dye configuration, we observe that the lifetime of both single dyes decreases as the size of the nanopore is reduced. The smallest nanopores yield an experimental Purcell Factor of 6. For the FRET pair configuration, we measure two regimes. For large nanopore sizes, the FRET efficiency remains constant. Whereas for smaller sizes, the FRET efficiency increases from 30 up to 45% with a decrease of the nanopore size. These findings, which have been supported by numerical simulations, may open new perspectives towards energy transfer engineering in plasmonic nanopores with potential applications in photonics and biosensing, in particular in single-molecule detection and sequencing. [less ▲]

Detailed reference viewed: 45 (5 UL)
Full Text
Peer Reviewed
See detailSite-Selective Integration of MoS2 Flakes on Nanopores by Means of Electrophoretic Deposition
Mosconi, Dario; Giovannini, Giorgia; Jacassi, Andrea et al

in ACS Omega (2019), 4(5), 9294-9300

Here, we propose an easy method for site-selective deposition of two-dimensional (2D) material flakes onto nanoholes by means of electrophoretic deposition. This method can be applied to both simple flat ... [more ▼]

Here, we propose an easy method for site-selective deposition of two-dimensional (2D) material flakes onto nanoholes by means of electrophoretic deposition. This method can be applied to both simple flat nanostructures and complex three-dimensional structures incorporating nano- holes. The deposition method is here used for the decoration of large ordered arrays of plasmonic structures with either a single or few layers of MoS2 . In principle, the plasmonic field generated by the nanohole can significantly interact with the 2D layer leading to enhanced light−material interaction. This makes our platform an ideal system for hybrid 2D material/ plasmonic investigations. The engineered deposition of 2D materials on plasmonic nanostructures is useful for several important applications such as enhanced light emission, strong coupling, hot-electron generation, and 2D material sensors. Site-selective integration of MoS2 flakes on nanopores by means of electrophoretic deposition. [less ▲]

Detailed reference viewed: 69 (2 UL)
Full Text
Peer Reviewed
See detailPlasmonic Nanopore Prepared on MoS2 Membrane - Hybrid Nanostructures Based on Site Selective Deposition
Mosconi, Dario; Miele, Ermanno; Giovannini, Giovannini et al

in Proceedings of SPIE : The International Society for Optical Engineering (2019), 10894

Here, we propose easy and robust strategies for the versatile integration 2D material flakes on plasmonic nanoholes by means of site selective deposition of MoS2. The methods can be applied both to simple ... [more ▼]

Here, we propose easy and robust strategies for the versatile integration 2D material flakes on plasmonic nanoholes by means of site selective deposition of MoS2. The methods can be applied both to simple metallic flat nanostructures and to complex 3D metallic structures comprising nanoholes. The deposition methods allow the decoration of large ordered arrays of plasmonic structures with single or few layers of MoS2. We show that the plasmonic field generated by the nanohole can interact significantly with the 2D layer, thus representing an ideal system for hybrid 2DMaterial/ Plasmonic investigation. The controlled/ordered integration of 2D materials on plasmonic nanostructures opens a pathway towards new investigation of the following: enhanced light emission; strong coupling from plasmonic hybrid structures; hot electron generation; and sensors in general based on 2D materials. [less ▲]

Detailed reference viewed: 49 (0 UL)
Full Text
Peer Reviewed
See detailPlasmonic zero mode waveguide for highly confined and enhanced fluorescence emission
Ponzellini, Paolo; Zambrana-Puyalto, Xavier; Maccaferri, Nicolò UL et al

in Nanoscale (2018), 10(36), 17362-17369

We fabricate a plasmonic nanoslot that is capable of performing enhanced single molecule detection at 10 muM concentrations. The nanoslot combines the tiny detection volume of a zero-mode waveguide and ... [more ▼]

We fabricate a plasmonic nanoslot that is capable of performing enhanced single molecule detection at 10 muM concentrations. The nanoslot combines the tiny detection volume of a zero-mode waveguide and the field enhancement of a plasmonic nanohole. The nanoslot is fabricated on a bi-metallic film formed by the sequential deposition of gold and aluminum on a transparent substrate. Simulations of the structure yield an average near-field intensity enhancement of two orders of magnitude at its resonant frequency. Experimentally, we measure the fluorescence stemming from the nanoslot and compare it with that of a standard aluminum zero-mode waveguide. We also compare the detection volume for both structures. We observe that while both structures have a similar detection volume, the nanoslot yields a 25-fold fluorescence enhancement. [less ▲]

Detailed reference viewed: 37 (4 UL)
Peer Reviewed
See detailHelical light emission from plasmonic vortices via magnetic tapered tip
Maccaferri, Nicolò UL; Gorodetski, Yuri; Garoli, Denis

in Journal of Physics. Conference Series (2018), 961

We investigate an architecture where a plasmonic vortex excited in a gold surface propagates on an adiabatically tapered magnetic tip and detaches to the far-field while carrying a well-defined optical ... [more ▼]

We investigate an architecture where a plasmonic vortex excited in a gold surface propagates on an adiabatically tapered magnetic tip and detaches to the far-field while carrying a well-defined optical angular momentum. We analyze the out-coming light and show that, despite generally high losses of flat magnetic surface, our 3D structure exhibits high energy throughput. Moreover, we show that once a magneto-optical activity is activated inside the magnetic tip a modulation of the total power transmittance is possible. [less ▲]

Detailed reference viewed: 51 (1 UL)
Full Text
Peer Reviewed
See detailLive Intracellular Biorthogonal Imaging by Surface Enhanced Raman Spectroscopy using Alkyne-Silver Nanoparticles Clusters
Ardini, Matteo; Huang, Jian-An; Sanchez, Carlos S. et al

in Scientific Reports (2018), 8

Live intracellular imaging is a valuable tool in modern diagnostics and pharmacology. Surface Enhanced Raman Spectroscopy (SERS) stands out as a non-destructive and multiplexed technique, but ... [more ▼]

Live intracellular imaging is a valuable tool in modern diagnostics and pharmacology. Surface Enhanced Raman Spectroscopy (SERS) stands out as a non-destructive and multiplexed technique, but intracellular SERS imaging still suffers from interfering background from endogenous components. Here we show the assembly of small colloidal SERS probes with Raman signal in the cell-silent window of 1800–2900 cm−1 for biorthogonal intracellular SERS imaging of dopamine that was undistinguishable from the endogenous cell background. By linking colloidal silver nanoparticles with alkyne-dopamine adducts, clusters are formed by 2–6 nanoparticles spaced by tight interparticle gaps that exhibited high electric field enhancement and strong SERS signals of alkyne and dopamines. Due to the cell-silent signals of the alkyne, intracellular in-vitro Raman imaging shows that the dopamines on the internalized clusters remain distinguishable across the cytoplasm with good spatial resolution. Our method can be a general-purpose method for real-time imaging of biomolecules, such as proteins, peptides, DNA and drugs. [less ▲]

Detailed reference viewed: 58 (2 UL)
Full Text
Peer Reviewed
See detailHybrid plasmonic nanostructures based on controlled integration of MoS2 flakes on metallic nanoholes
Garoli, Denis; Mosconi, Dario; Miele, Ermanno et al

in Nanoscale (2018), 10(36), 17105-17111

Here, we propose an easy and robust strategy for the versatile preparation of hybrid plasmonic nanopores by means of controlled deposition of single flakes of MoS2 directly on top of metallic holes. The ... [more ▼]

Here, we propose an easy and robust strategy for the versatile preparation of hybrid plasmonic nanopores by means of controlled deposition of single flakes of MoS2 directly on top of metallic holes. The device is realized on silicon nitride membranes and can be further refined by TEM or FIB milling to achieve the passing of molecules or nanometric particles through a pore. Importantly, we show that the plasmonic enhancement provided by the nanohole is strongly accumulated in the 2D nanopore, thus representing an ideal system for single-molecule sensing and sequencing in a flow-through configuration. Here, we also demonstrate that the prepared 2D material can be decorated with metallic nanoparticles that can couple their resonance with the nanopore resonance to further enhance the electromagnetic field confinement at the nanoscale level. This method can be applied to any gold nanopore with a high level of reproducibility and parallelization; hence, it can pave the way to the next generation of solid-state nanopores with plasmonic functionalities. Moreover, the controlled/ordered integration of 2D materials on plasmonic nanostructures opens a pathway towards new investigation of the following: enhanced light emission; strong coupling from plasmonic hybrid structures; hot electron generation; and sensors in general based on 2D materials. [less ▲]

Detailed reference viewed: 36 (2 UL)
Peer Reviewed
See detailNanoporous gold decorated with silver nanoparticles as large area efficient SERS substrate
Ardini, Matteo; Huang, Jian-An; Sanchez-Sanchez, Carlos et al

in Proceedings of SPIE : The International Society for Optical Engineering (2017), 10346

Nanoporous gold is a very promising material platform for several plasmonic applications. Nanoporous gold can be formed by dealloying Au–Ag alloys, previously grown by means of Ag-Au co-sputtering. The ... [more ▼]

Nanoporous gold is a very promising material platform for several plasmonic applications. Nanoporous gold can be formed by dealloying Au–Ag alloys, previously grown by means of Ag-Au co-sputtering. The optical response is completely determined by the nanostructured film features, that only depend on the initial alloy composition. It has been extensively used as SERS substrate both as thin film and nanofabricated fancy designs. Here we explore the potential application of nanoporous gold as SERS substrate as it is coupled and decorated with Ag nanoparticles. Significant enhancement has been observed in comparison with bare nanoporous film. [less ▲]

Detailed reference viewed: 51 (0 UL)
Peer Reviewed
See detailMagnetoplasmonic control of plasmonic vortices
Maccaferri, Nicolò UL; Gorodetski, Yuri; Toma, Andrea et al

in Applied Physics Letters (2017), 111(20), 201104

We theoretically investigate the generation of far-field propagating optical beams with a desired orbital angular momentum by using an archetypical magnetoplasmonic tip surrounded by a gold spiral slit ... [more ▼]

We theoretically investigate the generation of far-field propagating optical beams with a desired orbital angular momentum by using an archetypical magnetoplasmonic tip surrounded by a gold spiral slit. The use of a magnetic material can lead to important implications once magneto-optical activity is activated through the application of an external magnetic field. The physical model and the numerical study presented here introduce the concept of magnetically tunable plasmonic vortex lens, namely a magnetoplasmonic vortex lens, which ensures a tunable selectivity in the polarization state of the generated nanostructured beam. The presented system provides a promising platform for a localized excitation of plasmonic vortices followed by their beaming in the far-field with an active modulation of both light's transmission and helicity. Published by AIP Publishing. [less ▲]

Detailed reference viewed: 36 (4 UL)